Hexakis(1H-imidazole-κN3)iron(II) sulfate–1H-imidazole (1/2)
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چکیده
منابع مشابه
Cholinesterase-like organocatalysis by imidazole and imidazole-bearing molecules
Organocatalysis, which is mostly explored for its new potential industrial applications, also represents a chemical event involved in endogenous processes. In the present study, we provide the first evidence that imidazole and imidazole derivatives have cholinesterase-like properties since they can accelerate the hydrolysis of acetylthiocholine and propionylthiocholine in a concentration-depend...
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The asymmetric unit of the title compound, C(3)H(5)N(2) (+)·C(6)H(2)N(3)O(7) (-)·C(3)H(4)N(2)·H(2)O or H(C(3)H(4)N(2))(2) (+)·C(6)H(2)N(3)O(7) (-)·H(2)O, contains a diimidazolium cationic unit, one picrate anion and one mol-ecule of water. In the crystal, the components are connected by N-H⋯O, N-H⋯N and O-H⋯O hydrogen bonds, forming a two-dimensional network parallel to (001). In addition, weak...
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cus aureus by heat shock. The effect has then been more thoroughly investigated by landolo and Ordal (5, 6). Since heat shock causes an increased sensitivity of fungal cells to high temperature and blue light (2-4), it seemed justified also to test the response of heat-shocked fungal cells to high concentrations of sodium chloride. Most experiments were performed with the ascomycete Ophiostoma ...
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In the title compound, [Fe(C(5)H(5))(C(9)H(9)N(2))], the distances of the Fe atom from the centroids of the unsubstituted and the substituted cyclo-penta-dienyl (cp) rings are 1.639 (1) and 1.647 (1) Å, respectively. The ferrocenyl unit deviates from an eclipsed geometry with tilted cp rings; the inter-planar angle between the cp and imidazole rings is 114.11 (4)°.
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According to data on the imidazole antimycotics at present on the market, none of these products satisfactorily fills the gaps which exist in the treatment for mycoses of internal organs, although they have brought considerable progress in the topical treatment of mycoses. On the basis of their very broad spectrum and high intensity of activity under suitable test conditions, and the comparativ...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811043169